Analysis of marine motor oils using dielectric permittivity relaxation
https://doi.org/10.46845/1997-3071-2023-71-131-144
Abstract
During exploitation of marine engine oil, its aging occurs, the main factors of which are oxidative high-temperature degradation and contamination with soot, wear metals, fuel, water and coolant. In this work, a number of used marine oils have been studied by relaxation dielectric spectroscopy to determine their characteristics associated with lubricant degradation and engine wear. For marine oils Total DISOLA M4015, Shell Rimula, Mobil 5W40, Mobil 10W40, Navigo TPEO 12/40, the dependences of the relative permittivity and the tangent of the loss angle on frequency have been experimentally obtained. The dielectric constant of marine motor oils ranges from 2.1 to 2.4 and depends on the viscosity, density of the oil, the content of paraffin, naphthenic and aromatic compounds in it and the additive package. An increase in the additive content increases the dielectric constant of the oil. The authors investigated the relationship of the dipole relaxation times of fresh and used oils with kinematic viscosity, with the content of additives and wear products. The desired array of relaxation time distributions has been calculated by regularization and the least squares method using the CONTIN algorithm. The calculations have been carried out in the RILT program running in the MatLab environment. It has been shown that polarization and subsequent dipole relaxation are caused by additive molecules that are triggered during engine operation. Differences in relaxation times can also be caused by the formation of associations involving dipole molecules. The data obtained in the work can be used in the future to build an expert engine diagnostics system and to determine the parameters of unknown oils.
About the Authors
O. V. Synashenko
Kaliningrad State Technical University
Russian Federation
Russian Federation
Oksana V. Synashenko, PhD in Physical and Mathematical sciences, Associate Professor
Department of Physics
Kaliningrad
N. Ya. Sinyavskiy
Kaliningrad State Technical University
Russian Federation
Russian Federation
Nikolay Ya. Sinyavskiy, Doctor of Physical and Mathematical sciences, Professor, Head of the Department
Department of Physics
Kaliningrad
N. A. Kostrikova
Kaliningrad State Technical University
Russian Federation
Russian Federation
Natal’ya A. Kostrikova, PhD in Physical and Mathematical sciences, Associate Professor, Vice-rector for Research
Kaliningrad
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Review
For citations:
Synashenko O.V., Sinyavskiy N.Ya., Kostrikova N.A. Analysis of marine motor oils using dielectric permittivity relaxation. KSTU News. 2023;(71):131-144. (In Russ.) https://doi.org/10.46845/1997-3071-2023-71-131-144
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